LaBonia, Gabriel J. (2014) Synthesis and Characterization of a New Bimetallic Catalyst, GJL-46, and Its Use in the Catalytic Hydrosilylation of Phenylacetylene. Undergraduate thesis, under the direction of T. Keith Hollis from Chemistry & Biochemistry, The University of Mississippi.
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Abstract
A new bimetallic catalyst was synthesized from the metalation of 1,1'-(1,3-phenylene) bis(4-butyl-1 H-1,2,4-triazol-4-ium) iodide with silver oxide and the transmetalation of that complex with Rh(COD)2OTf. The structure of the compound, GJL-46, with molecular formula C34H46I2N6Rh2, was confirmed with mass spectra analysis, 1H NMR and 13C NMR. The catalytic activity of the produced molecule, GJL-46, with molecular formula C34H46I2N6Rh2, in the hydrosilylation of phenylacetylene is reported.
| Item Type: | Thesis (Undergraduate) |
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| Creators: | LaBonia, Gabriel J. |
| Student's Degree Program(s): | B.S. Forensic Chemistry |
| Thesis Advisor: | T. Keith Hollis |
| Thesis Advisor's Department: | Chemistry & Biochemistry |
| Institution: | The University of Mississippi |
| Subjects: | Q Science > QD Chemistry |
| Depositing User: | Mr Gabriel LaBonia |
| Date Deposited: | 29 Apr 2014 13:46 |
| Last Modified: | 29 Apr 2014 13:46 |
| URI: | http://thesis.honors.olemiss.edu/id/eprint/37 |
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