Effects of Halogen Bonding on 13C NMR Shifts of Iodotolan

Long, James (2019) Effects of Halogen Bonding on 13C NMR Shifts of Iodotolan. Undergraduate thesis, under the direction of Daniell Mattern from Chemistry and Biochemistry, The University of Mississippi.

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Abstract

Halogen bonding is the ability of heavier halogens to have noncovalent interactions similar to hydrogen bonding. By mixing two compounds that should halogen bond together and analyzing this mixture with carbon NMR spectroscopy, we attempted to test the strength and extent of halogen bonding in 4-iodotolan. After observing the changes in the 4-iodotolans chemical shifts, the halogen bond appears to be too weak to affect the chemical shifts in a substantial manner; however, the C-I bonded carbon shows a slight but consistent increase in its shift which could be an avenue for future research.

Item Type: Thesis (Undergraduate)
Creators: Long, James
Student's Degree Program(s): B.A. in Computer Science
Thesis Advisor: Daniell Mattern
Thesis Advisor's Department: Chemistry and Biochemistry
Institution: The University of Mississippi
Subjects: Q Science > QD Chemistry
Depositing User: James Long
Date Deposited: 10 May 2019 17:52
Last Modified: 10 May 2019 17:52
URI: http://thesis.honors.olemiss.edu/id/eprint/1442

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